OnLive's service doesn't seem to be limited in any ways on Ouya, with the announcement stating OnLive "will deliver a full console-classe experience, bringing hundreds of top-tier games from more than 80 publishers to the Ouya console for play on demand." The service is also detailed as "the same OnLive experience," which sounds an awful lot like it'll have the same library available through OnLive elsewhere.
Beyond the partnership announcement, we've got some new images of the console, its controller (both halves!), and the UI. Take a peek in our gallery below!%Gallery-161237%