Happily, NCsoft has updated its PowerWiki with a lengthy entry devoted to answering all of your daily quest needs. Everything from where to get to them, to what kind of rewards they offer, to how to join the requisite NPC factions, is available in the new article.
"Every morning at 9 o'clock, the organization will send a new Quest notice that can be found at the bottom of your screen. Once you click on the icon, you can choose to either accept or decline the Daily Quest. If you accidentally decline the Quest, you can quit and then re-join the organization to get it again," the article says.
Check out all the details over at the official Aion PowerWiki.