Wowhead reports that Heart of the Valorous stacks with Valor of the Ancients. With both buffs active, a daily quest that normally awards 5 Valor Points yields 12 Valor Points instead.
Patch 5.4.8 introduces Heart of the Valorous

A. Ziebart|05.16.14
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Wowhead reports that Heart of the Valorous stacks with Valor of the Ancients. With both buffs active, a daily quest that normally awards 5 Valor Points yields 12 Valor Points instead.